3-Chloro-2-methylaniline
Structural formula
| Business number | 01Y6 |
|---|---|
| Molecular formula | C7H8ClN |
| Molecular weight | 141 |
| label |
2-Chloro-6-aminotoluene, 3-Chloro-o-toluidine, o-Methyl m-chloroaniline, 2-Amino-6-chlorotoluene, 3-Chloro-o-toluidine |
Numbering system
CAS number:87-60-5
MDL number:MFCD00007766
EINECS number:201-756-6
RTECS number:XU4760000
BRN number:471697
PubChem number:24846547
Physical property data
1. Character: liquid, can be Water vapor evaporates and quickly turns brown in the air 2. Density (g/mL,25/4℃): 1.171 3. Relative vapor density (g/mL,air =1): Undetermined 4. Melting point (ºC): 2℃ 5. Boiling point (ºC,Normal pressure): 245℃ (ºC,0.67kpa or 5 mmHg) 6. Boiling point (ºC,5.2kPa): 115-117℃ (ºC,1.33kpa) 7. Refractive index: 1.588-1.59 8. Flashpoint (ºC): 112.8℃ 9. Specific optical rotation (º) : Undetermined 10. Autoignition point or ignition temperature (ºC): Undetermined 11. Vapor pressure (kPa,25ºC): Undetermined 12. Saturation vapor pressure (kPa,60ºC): Undetermined 13. Burning heat (KJ/mol): Undetermined 14. Critical temperature (ºC): Undetermined 15. Critical pressure (KPa): Undetermined 16. Oil and water (octanol/Log value of the partition coefficient for water: undetermined <SPAN style="mso-list: Ign��Number: 9 8. Surface charge: 0 9. Complexity: 94.9 10. Number of isotope atoms: 0 11. Determine the number of atomic stereocenters: 0 12. Uncertain number of atomic stereocenters: 0 13. Determine the number of chemical bond stereocenters: 0 14. Number of uncertain chemical bond stereocenters: 0 15. Number of covalent bond units: 1
Properties and stability
None yet
Storage method
This product is sealed and stored in a cool, dry place.
Synthesis method
By O-nitrotoluene is obtained by chlorination and reduction. 1.Chlorinated in o-nitrotoluene , add 2% Iron acts as a catalyst in50-60℃ Pour in chlorine until the relative density of the reaction solution reaches1.27-1.29（50℃) Until now, use 5% Hydrochloric acid washing, and then Wash with water, and finally adjust the pH with liquid alkalipH for7. Separate the water layer, evaporate the water, and conduct vacuum distillation to collect120-150℃（) fraction, cool, crystallize and filter to obtain2-chlorine-6-Nitrotoluene. 2.Reduction Add hydrochloric acid and iron powder Stir and heat in the reaction pot until 90℃ , slowly add the melted2-Chlorine -6-Nitrotoluene, added , reflux reaction3h. Cool, add liquid alkali to adjustpH is8, steam distilled, get 3-Chloro-o-toluidine.
Purpose
Organic synthesis intermediates.
Add acid and iron powder to the reaction pot, stir and heat until 90℃, slowly add the melted2-Chlorine-6 –Nitrotoluene, addition completed, reflux reaction3h. Cool, add liquid alkali to adjustpH is8, steam distilled, get 3-Chloro-o-toluidine.
Purpose
Organic synthesis intermediates.