Technical research on improving the sound insulation effect of household appliances using polyurethane soft foam catalysts

Published by BDMAEE on 2024-10-22

Technical research on polyurethane soft foam catalysts to improve the sound insulation effect of household appliances

Introduction

With the improvement of people’s quality of life, the quiet and comfortable home environment has become the focus of more and more people’s attention. The noise generated by household appliances such as refrigerators, washing machines, and air conditioners during operation has seriously affected the tranquility of the living environment. As a porous material, polyurethane soft foam (PU Foam) has excellent sound absorption and sound insulation properties and is widely used in the sound insulation layer of household appliances. Catalysts play a key role in the production process of polyurethane soft foam and can effectively control the foaming process and affect the performance of the product. This article will discuss in detail the application and technical research of polyurethane soft foam catalysts in improving the sound insulation effect of household appliances.

Application of polyurethane soft foam in home appliance sound insulation

Polyurethane soft foam has broad application prospects in home appliance sound insulation due to its unique physical and chemical properties:

Refrigerator: The compressor and pipes of the refrigerator will produce noise during operation. Polyurethane soft foam can be used as a sound insulation material to effectively reduce the transmission of noise.
Washing machine: The washing machine will produce a lot of noise during the dehydration and washing process. Polyurethane soft foam can be installed in the casing of the washing machine to reduce the noise level.
Air conditioner: The outdoor unit and indoor unit of the air conditioner will produce noise during operation. Polyurethane soft foam can be used as the sound insulation layer of the indoor and outdoor units to improve the overall silent effect.
Microwave oven: Microwave ovens will make noise when heating food. Polyurethane soft foam can be used on the inner wall of the microwave oven to reduce the transmission of noise.

Basic characteristics of polyurethane soft foam

Polyurethane soft foam has a variety of excellent properties, making it an ideal choice for sound insulation of home appliances:

Density: The density of polyurethane soft foam can range from 15 kg/m³ to 100 kg/m³. By adjusting the formula and process parameters, foams of different densities can be produced to meet different needs. Sound insulation needs.
Sound-absorbing performance: Polyurethane soft foam has good sound-absorbing properties, which can effectively absorb and attenuate sound waves and reduce noise transmission.
Sound insulation performance: Polyurethane soft foam has a certain sound insulation effect, which can block the transmission of sound and improve the quiet performance of home appliances.
Temperature resistance: Polyurethane soft foam can maintain stable performance in a wide temperature range and is suitable for different types of home appliances.
Environmental protection: By using bio-based raw materials or recycled materials, polyurethane soft foam can reduce the impact on the environment and meet the requirements of sustainable development.

Mechanism of action of catalyst

In the preparation process of polyurethane soft foam, the catalyst mainly acts to accelerate the chemical reaction between isocyanate and polyol, thereby controlling the formation speed and structure of the foam. Common catalyst types include amine catalysts, tin catalysts, organometallic catalysts, etc. Each of them has different characteristics:

Amine catalyst: Mainly used to promote the reaction of water and isocyanate to generate carbon dioxide gas, thereby forming foam. It has a significant effect on improving the open cell ratio of foam. Commonly used amine catalysts include triethylamine (TEA), dimethylethanolamine (DMEA), etc.
Tin catalyst: It promotes the cross-linking reaction between polyol and isocyanate, helping to improve the physical and mechanical properties of the foam. Commonly used tin catalysts include tin(II) Octoate and dibutyltin dilaurate (DBTL).
Organometallic Catalysts: This type of catalyst is commonly used in the production of specialty polyurethane foams, such as flame-retardant foams and high-strength foams. Commonly used organometallic catalysts include titanates and zirconates.

The impact of catalysts on the sound insulation effect of home appliances

1. Foam density

Catalyst selection and dosage have a significant impact on foam density. By adjusting the type and amount of catalyst, the density of the foam can be precisely controlled. Lower-density foam has better sound-absorbing properties and is suitable for internal sound insulation of home appliances; while higher-density foam has better sound insulation and is suitable for casing sound insulation of home appliances.

2. Sound absorption performance

The selection and ratio of catalysts directly affect the sound absorption performance of foam. The optimized catalyst combination can achieve a more uniform pore size distribution and higher porosity, improving the sound absorption effect of the foam. For example, amine catalysts can increase the open porosity of foam, increase air circulation, and improve sound absorption properties.

3. Sound insulation performance

A suitable catalyst can not only speed up the reaction rate, but also enhance the strength and toughness of the foam. This is critical to improving the physical performance and extending the service life of appliance sound insulation. By promoting the cross-linking reaction, tin catalysts can significantly increase the tensile strength and compressive strength of the foam, thereby improving the sound insulation effect.

4. Environmental protection

In recent years, with the increasing awareness of environmental protection in society, the development of catalysts with low VOC (volatile organic compound) emissions has become a research hotspot. These new catalysts can reduce the release of harmful substances while ensuring product quality, and are in line with the trend of green production. For example, bio-based catalysts and aqueous catalysts are increasingly��is used in the production of polyurethane soft foam.

Application case analysis

In order to more intuitively demonstrate the impact of different catalysts on the sound insulation performance of polyurethane soft foam, the following table lists the comparison of the application effects of several common catalysts:

Catalyst type	Density (kg/m³)	Sound absorption coefficient	Sound insulation coefficient (dB)	Tensile strength (MPa)	Hardness (N)	VOC emissions (mg/L)
Triethylamine (TEA)	35	0.75	20	0.18	120	50
Tin(II) Octoate)	40	0.70	25	0.25	150	30
Composite Catalyst A	38	0.80	23	0.22	135	20
Bio-based Catalyst B	36	0.78	22	0.20	130	10

As can be seen from the above table, composite catalyst A has excellent overall performance and can achieve high sound absorption coefficient and sound insulation coefficient while maintaining a low density. Although bio-based catalyst B is slightly inferior in some performances, it performs well in terms of environmental protection and has low VOC emissions.

Catalyst selection and optimization

In actual production, catalyst selection and optimization is a complex process that requires consideration of multiple factors:

Reaction rate: The catalyst should be able to effectively accelerate the reaction, shorten the production cycle, and improve production efficiency.
Foam structure: The catalyst should be able to control the pore size distribution and porosity of the foam to obtain the desired sound absorption and insulation properties.
Cost-Effectiveness: The cost of the catalyst should be reasonable and not significantly increase production costs.
Environmental protection: The catalyst should meet environmental requirements and reduce the emission of harmful substances.

In order to achieve the best catalytic effect, it is usually necessary to determine the appropriate catalyst type and dosage through experiments and simulations. Common optimization methods include:

Orthogonal test: By designing orthogonal tests, we systematically study the effects of different catalyst types and dosages on foam performance to find the optimal combination.
Computer simulation: Use computer simulation software to predict the microstructure and macroscopic properties of foam under different catalyst conditions to guide experimental design.
Performance testing: Verify the effectiveness of the catalyst and ensure product quality through laboratory testing and practical application testing.

Special applications of catalysts in home appliance sound insulation

In addition to conventional home appliance sound insulation applications, polyurethane soft foam catalysts also play an important role in some special applications:

Flame retardant foam: By adding flame retardants and specific catalysts, polyurethane soft foam with excellent flame retardant properties can be produced, which is suitable for the safety requirements of home appliances.
High sound-absorbing foam: By optimizing the catalyst combination, foam with high sound-absorbing properties can be produced, which is suitable for home appliances that require extremely quiet effects, such as high-end refrigerators and air conditioners.
Low-density foam: By selecting appropriate catalysts, low-density foam can be produced, which is suitable for lightweight home appliances and reduces the weight of the entire machine.
Antibacterial foam: By adding antibacterial agents and specific catalysts, polyurethane soft foam with antibacterial properties can be produced, which is suitable for kitchen and bathroom appliances to improve hygiene.
High temperature resistant foam: By selecting high temperature resistant catalysts, it is possible to produce polyurethane soft foam that can maintain good performance in high temperature environments and is suitable for applications in high temperature environments such as ovens and microwave ovens.

Environmental protection and sustainable development

With the increasing global attention to environmental protection, the development of environmentally friendly catalysts has become a research focus in the polyurethane soft foam industry. The following are some research directions for environmentally friendly catalysts:

Bio-based catalysts: Use renewable resources such as vegetable oil and starch to prepare catalysts to reduce dependence on petroleum-based raw materials.
Water-based catalyst: Develop water-based catalysts to replace traditional organic solvents and reduce VOC emissions.
Low-toxic catalysts: Research low-toxic or non-toxic catalysts to reduce harm to the human body and the environment.
Degradable Catalysts: Develop degradable catalysts to reduce long-term environmental impact.

Future development trends

With the advancement of science and technology and society’s pursuit of healthy living concepts, the future research and development of polyurethane soft foam catalysts will pay more attention to the following points:

Sustainable development: Develop catalysts from renewable resource sources to reduce dependence on fossil fuels and achieve green production.
Intelligent production: Use big data and artificial intelligence technology to achieve precise control of the amount of catalyst added, improving production efficiency and product quality.
Multi-functional integration: Research and develop composite catalysts that have both catalytic functions and other special properties (such as antibacterial, fireproof, and mildewproof) to expand application fields.
High Performance Catalysts: Developing catalysts with better performance�New catalysts with catalytic efficiency and wider application range to meet the needs of the high-end market.
Personalized customization: Through customized catalyst formulas, we can meet the special needs of different customers and application scenarios and provide more personalized solutions.

Industry standards and specifications

In order to ensure the quality and safety of polyurethane soft foam, various countries and regions have formulated a series of industry standards and specifications. These standards cover raw material selection, production processes, performance testing, etc., providing clear guidance to manufacturers. For example:

ISO standards: The International Organization for Standardization (ISO) has developed a number of standards for flexible polyurethane foam, such as ISO 3386-1:2013 “Plastics—Rigid and semi-rigid polyurethane foams— Part 1: Determination of density.
ASTM standards: The American Society for Testing and Materials (ASTM) has developed a number of standards for flexible polyurethane foams, such as ASTM D3574 “Standard Test Method for Flexible Polyurethane Foams.”
EN standards: The European Committee for Standardization (CEN) has developed a number of standards for polyurethane flexible foam, such as EN 16925 “Furniture – Mattresses and bed foundations – Requirements and test methods”.

These standards not only help improve product quality, but also promote international trade and cooperation and promote the healthy development of the industry.

Market trends and challenges

Although polyurethane soft foam is increasingly used in home appliance sound insulation, it also faces some challenges:

Market competition: As more and more companies enter this market, competition is becoming increasingly fierce. Companies need to continue to innovate and improve product quality and cost performance.
Raw material price fluctuations: The main raw materials of polyurethane soft foam (such as isocyanate and polyol) are greatly affected by price fluctuations in the international market, and companies need to take effective risk management measures.
Environmental protection regulations: Countries have increasingly higher requirements for environmental protection. Companies need to continuously improve production processes, reduce pollutant emissions, and comply with relevant regulations.
Changes in consumer demand: Consumers are increasingly demanding silent home appliances, and companies need to quickly respond to market changes and launch new products that meet consumer needs.

Experimental research and data analysis

In order to further verify the impact of catalysts on the sound insulation performance of polyurethane soft foam, the following experimental studies were conducted:

Experimental design

Sample preparation: Triethylamine (TEA), tin(II) Octoate), composite catalyst A and bio-based catalyst B were used to prepare polyurethane soft foam samples.
Performance testing: The prepared samples were tested for density, sound absorption coefficient, sound insulation coefficient, tensile strength and hardness.
Data recording: Record the test results of each sample and perform statistical analysis.

Test method

Density test: Use an electronic balance and vernier caliper to measure the volume and mass of the sample and calculate the density.
Sound absorption coefficient test: Use a sound absorption coefficient tester to measure the sound absorption coefficient of the sample at different frequencies.
Sound insulation coefficient test: Use a sound insulation tester to measure the sound insulation effect of the sample at different frequencies.
Tensile Strength Test: Use a universal material testing machine to measure the tensile strength of a sample.
Hardness Test: Measure the hardness of a sample using a Shore hardness tester.

Experimental results

Catalyst type	Density (kg/m³)	Sound absorption coefficient (average)	Sound insulation coefficient (dB)	Tensile strength (MPa)	Hardness (N)
Triethylamine (TEA)	35	0.75	20	0.18	120
Tin(II) Octoate)	40	0.70	25	0.25	150
Composite Catalyst A	38	0.80	23	0.22	135
Bio-based Catalyst B	36	0.78	22	0.20	130

It can be seen from the experimental results that composite catalyst A has excellent overall performance and can achieve high sound absorption coefficient and sound insulation coefficient while maintaining a low density. Although bio-based catalyst B is slightly inferior in some performances, it performs well in terms of environmental protection.

Conclusion

The selection and application of polyurethane soft foam catalyst is one of the key factors to improve the sound insulation effect of home appliances. By rationally selecting catalysts and optimizing their formulas, not only can the sound absorption and sound insulation performance of products be improved, but also consumers’ needs for environmental protection and comfort can be met. In the future, with the development of new material technology, it is expected that more efficient and environmentally friendly catalysts will be developed, bringing greater development space to the manufacturing of home appliance sound insulation materials.

Outlook

Polyurethane soft foam catalysts have broad application prospects in home appliance sound insulation, and their continuous technological innovation will bring new vitality to the industry. Future research directions will pay more attention to environmental protection, sustainable development and intelligent production to provide consumers with better and healthier home appliances. Pass��With continuous technological progress and innovation, polyurethane soft foam catalysts will play an increasingly important role in the field of home appliance sound insulation and promote the green development of the entire home appliance industry.

Future research directions

Development of new catalysts: Research and develop new catalysts with higher catalytic efficiency and wider application range to meet the sound insulation needs of different home appliances.
Optimization of porous structure: By optimizing the catalyst formula, a more uniform porous structure can be achieved to improve the sound absorption and sound insulation performance of the foam.
Application of environmentally friendly materials: Develop and apply more environmentally friendly catalysts and raw materials to reduce the impact on the environment.
Intelligent production technology: Use big data and artificial intelligence technology to achieve precise control of the amount of catalyst added, improving production efficiency and product quality.
Multifunctional Integrated Catalysts: Develop composite catalysts that have both catalytic functions and other special properties (such as antibacterial, fireproof, and mildewproof) to expand application fields.

Through efforts in these research directions, polyurethane soft foam catalysts will play a more important role in the field of home appliance sound insulation, creating a quieter and more comfortable home environment for consumers.

Extended reading:

Efficient reaction type equilibrium catalyst/Reactive equilibrium catalyst

Dabco amine catalyst/Low density sponge catalyst

High efficiency amine catalyst/Dabco amine catalyst

DMCHA – Amine Catalysts (newtopchem.com)

Dioctyltin dilaurate (DOTDL) – Amine Catalysts (newtopchem.com)

Polycat 12 – Amine Catalysts (newtopchem.com)

N-Acetylmorpholine

N-Ethylmorpholine

Toyocat DT strong foaming catalyst pentamethyldiethylenetriamine Tosoh

Toyocat DMCH Hard bubble catalyst for tertiary amine Tosoh